He had previously appeared with Jack Lord in Lord's prior series Stoney Burke. Smith joined the cast of the final season of Hawaii Five-O as Detective James "Kimo" Carew, a new officer in the Five-O unit. Smith has been described as the "greatest bad-guy character actor of our time". On Gunsmoke, Smith appears in a 1972 episode, "Hostage!" his character beats and rapes Amanda Blake's character Miss Kitty Russell and shoots her twice in the back. In that story line, Brown takes the job of sheriff to tame a lawless town, begins to court a young woman (again played by Emily Banks) but soon returns to his deadly outlaw ways in search of bigger thrills. Smith also played the outlaw turned temporary sheriff Hendry Brown in the 1969 episode "The Restless Man". In the story line, Parker contracts the plague, is left for dead by his fellow Comanche warriors, and is rescued by his future Mexican wife, Yolanda (Emily Banks). Smith was cast as John Richard Parker, brother of Cynthia Ann Parker, both taken hostage in Texas by the Comanche, in the 1969 episode "The Understanding" of the syndicated television series Death Valley Days, which was hosted by Robert Taylor. In 1967, Smith guest starred as Jude Bonner on James Arness's long-lived western Gunsmoke. Smith's character was good-natured with muscles of steel. One of his earliest leading roles was as Joe Riley, a Texas Ranger on the NBC western series Laredo (1965–1967). He was a regular on the 1961 ABC television series The Asphalt Jungle, portraying police Sergeant Danny Keller. government, but his marriage to a French actress meant the loss of security clearance. He had both CIA and NSA clearance and intended to enter a classified position with the U.S. ĭuring the Korean War he was a Russian Intercept Interrogator and flew secret ferret missions over Russia. Smith is fluent in Russian, Serbo-Croatian, French and German. He also studied at the Sorbonne in Paris and the University of Munich while learning languages through the military. studies for a MGM contract and stunt doubling for the former Tarzan Lex Barker in the 1958 French film The Strange Awakening. He taught Russian at UCLA before abandoning his Ph.D. Smith earned a Bachelor of Arts from Syracuse University and a Master's degree in Russian Studies from UCLA. He also played semi-pro football in Germany and competed in motocross and downhill skiing events. Smith held a 31-1 record as an amateur boxer and studied martial arts with kenpo instructor Ed Parker for several years. Smith is a record holder for reverse-curling his own bodyweight. He won the 200 pound (91 kg) arm-wrestling championship of the world multiple times and also won the United States Air Force weightlifting championship. Smith served in the United States Air Force. Smith is a lifelong bodybuilder and has the distinction of being the final Marlboro Man before cigarette advertising was discontinued on television. Born in Columbia, Missouri, Smith began his acting career at the age of eight in 1942 he entered films as a child actor in such films as The Ghost of Frankenstein, The Song of Bernadette and Meet Me in St.
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That said, most people don’t need applications like CMM, others can do a lot of harm to their Macs by not paying attention to what you are asking CMM to do. If you have been looking for something to help you clean up your hard drive and improve performance on your computer, while also being able to scan for malicious files, then this is the program for you.Ĭlick here to find out more about CleanMyMac X.CleanMyMacX is a legitimate application, developed by MacPaw, who have been developing for Mac for decades. Getting all of these features from separate programs would easily cost you a lot more money, plus you’d have the system overhead that comes from installing so many separate programs.ĬleanMyMac X is sleek, doesn’t use a lot of resources, and comes from MacPaw, a longtime trusted utility provider for Macs. Overall, I find this to be a very handy program that’s well worth the cost.
Parallels Desktop for Mac helps you do just that! What Is Parallels for Mac ? This requires many people to look for alternative ways to use them. However, many professional, creativity, and development apps don't have native versions for macOS. The overall results indicate that most Apple fans would clearly be better served by the less expensive MacBook Pro 16 with M1 Pro SoC thanks to its seemingly superior price-performance ratio.Even if you are not a digital expert or a tech-savvy person, you would know that you cannot run a Microsoft Windows application on Mac devices. The new MacBook Pro 16 machines fall behind the 18-core iMac Pro in Cinebench R23 multi thanks to the eight extra cores the Intel Xeon W-2191B processor brings with it, but when it comes to Cinebench R23 single the M1 Pro and M1 Max chips are way ahead of the much-older iMac Pro and at the same level as the M1 MacBook Pro, demonstrating the benefits of the newer M1 Firestorm and Icestorm microarchitecture. Obviously the M1 Pro and M1 Max generally match in the CPU benchmarks, which include runs through Cinebench R23 and Geekbench 5. The host then proceeds to cover the 10-core CPU part that is found in both variants of the 2021 Apple Silicon. Additionally, in the Blender BMW GPU bench there is practically nothing between the two MacBooks, so as Miani points out, while the M1 Max MacBook Pro 16 would appeal to those who are involved in constant graphics-intensive tasks or for those who want to play games, the much-cheaper M1 Pro machine would likely be sufficient to cover the majority of use cases. However, in video-editing benchmarks such as Final Cut Pro and DaVinci Resolve, only a few seconds separates the M1 Pro device with the M1 Max laptop in file exporting and rendering. With twice the GPU cores, it’s expected that the M1 Max would overpower the M1 Pro in these particular benchmarks. It’s far ahead of the M1 Pro and also beats out other comparison devices, such as the 18-core iMac Pro and the 2020 iMac i7. In the real-world Shadow of the Tomb Raider game test, the M1 Max MacBook Pro 16 pulls off nearly 100 FPS while operating via Rosetta. The heavier M1 Max machine, which has a slightly higher weight because of its larger SoC heatsink, unsurprisingly proves to be a monster in graphics and GPU benchmarks, such as Geekbench compute and the various GFXBench tests. The results of the numerous benchmarks can be seen in the screenshots posted below, with Miani’s entertaining video also embedded beneath this article. Miani details how much the laptops cost, with the M1 Pro MacBook Pro 16 (16-core GPU, 16 GB RAM) costing US$2,699 and the M1 Max MacBook Pro 16 (32-core GPU, 64 GB RAM) requiring a payment of US$3,899. The M1 Max model was also tested in the same benchmarks in high-power mode, with the arguably disappointing results initially not shining a good light on this particular feature. The host put the MacBooks through 20 benchmarks to give viewers a thorough idea of just how powerful the new Apple laptops are. The popular TechTuber Luke Miani has posted a new video comparing an M1 Pro-based Apple MacBook Pro 16 with a model featuring the more-powerful M1 Max SoC and additional RAM. This style attempted to capture the wild realism of an unsettled America that was quickly disappearing, and the feelings of discovery and appreciation for natural beauty. The paintings were characterized by their focus on traditional American pastoral settings, especially the Catskill Mountains, and their romantic qualities. Cole, along with his friend Asher Durand, started this school in New York it was the first well-acknowledged American artistic movement. Both Cole and Church were devout Protestants and the latter's beliefs played a role in his paintings especially his early canvases. The Hudson River School was established by the British Thomas Cole when he moved to America and started painting landscapes, mostly of mountains and other traditional American scenes. Soon after, he sold his first major work to Hartford's Wadsworth Athenaeum.Ĭhurch was the product of the second generation of the Hudson River School and the pupil of Thomas Cole, the school’s founder. In May 1849, Church was elected as the youngest Associate of the National Academy of Design and was promoted to Academician the following year. At eighteen years of age, Church became the pupil of Thomas Cole in Catskill, New York after Daniel Wadsworth, a family neighbor and founder of the Wadsworth Athenaeum, introduced the two. The family's wealth allowed Frederic Church to pursue his interest in art from a very early age. Joseph later became an official and a director of The Aetna Life Insurance Company. Joseph, in turn, was the son of Samuel Church, who founded the first paper mill in Lee, Massachusetts in the Berkshires. The family's wealth came from Church's father, a silversmith and watchmaker in Hartford, Connecticut. Church was the son of Eliza (née Janes) and Joseph Church. In his later years, Church painted classical Mediterranean and Middle Eastern scenes and cityscapes.įrederic Edwin Church was a direct descendant of Richard Church, who was a Puritan pioneer from England who accompanied Thomas Hooker on the original journey through the wilderness from Massachusetts to what would become Hartford, Connecticut. Church's paintings put an emphasis on light and a Romantic respect for natural detail. He was a central figure in the Hudson River School of American landscape painters, perhaps best known for painting large panoramic landscapes, often depicting mountains, waterfalls, and sunsets, but also sometimes depicting dramatic natural phenomena that he saw during his travels to the Arctic and Central and South America. For more details please refer to our "Oil Paintings Reproductions FAQ".Frederic Edwin Church (– April 7, 1900) was an American landscape painter born in Hartford, Connecticut. Please visit our "Completed Paintings" to see side by side examples of our reproductions next to the originals. Our experienced artists paint in the same way the original paintings were created with visible textures and brush strokes. We do not use prints or computer generated manipulation when creating our paintings, each artwork is painted on a blank canvas from scratch. Our oil paintings are 100% real hand-painted paintings, on real thick canvas with real and finest quality oil paints. Hand painted with oils on canvas after museum original. 60" x 72" (150 x 180 cm) $799 Custom sizes: we can paint any size, contact us for a price quote if your desired size is not listed above. It is continued externally by electrons moving into the battery which constitutes positive current flowing outwards. This outward current is carried internally by positive ions moving from the electrolyte to the positive cathode (chemical energy is responsible for this "uphill" motion). Whether the cathode is negatively polarized (such as recharging a battery) or positively polarized (such as a battery in use), the cathode will draw electrons into it from outside, as well as attract positively charged cations from inside.Ī battery or galvanic cell in use has a cathode that is the positive terminal since that is where conventional current flows out of the device. Inside a device or a cell, positively charged cations always move towards the cathode and negatively charged anions move towards the anode, although cathode polarity depends on the device type, and can even vary according to the operating mode. The electrode through which conventional current flows the other way, into the device, is termed an anode.Ĭonventional current flows from cathode to anode outside of the cell or device (with electrons moving in the opposite direction), regardless of the cell or device type and operating mode.Ĭathode polarity with respect to the anode can be positive or negative depending on how the device is being operated. For example, the end of a household battery marked with a + (plus) is the cathode. Consequently, the mnemonic cathode current departs also means that electrons flow into the device's cathode from the external circuit. Electrons have a negative electrical charge, so the movement of electrons is opposite to that of the conventional current flow. A conventional current describes the direction in which positive charges move. This definition can be recalled by using the mnemonic CCD for Cathode Current Departs. Positively charged cations move towards the cathode allowing a positive current i to flow out of the cathode.Ī cathode is the electrode from which a conventional current leaves a polarized electrical device. Diagram of a copper cathode in a galvanic cell (e.g., a battery). Let me know if you have other concerns about managing customers and income transactions in QBO. It includes help articles, Community discussions with other users, and video tutorials, to name a few. Enter or add your or company's email address in the Copy (Cc) new invoices to address and Blind Copy (Bcc) new invoices to address fields.Īlso, you may want to check out one of our Help pages as your reference to guide you in managing your business growth and transactions using QBO: QuickBooks Learn and Support.Click anywhere in the Messages section to open its details.On the other hand, in case you want to receive a copy of the new invoices you create in QBO, you can add your or company's email in the Copy (Cc) new invoices to address or Blind Copy (Bcc) new invoices to address fields in the Account and Settings page.
Maybe the musical rat lost any and all animal instinct during the awakening ritual (thus now having a lower Wisdom score) and is now totally unable to relate to fellow rats as he drowns in the praise of humanoid fans. Likewise, no one aside from the truly exceptional has decent stats across the board (as many animals have good Strength, Dexterity, and Constitution already) so I think we should lower one for the sake of balance and to show the creature’s personality more. I think it would fun to have some variety in our awakened creatures and sort out which ones have the innate talent to learn new things (like a rat with high Charisma becoming a world-renowned musician, for example). Monster Tags: Misc Creature Environment: Forest Basic Rules, pg. Lastly the DM chooses two of the three “mental” ability scores and raises one by 1d4 points and lowers another by 1d4 points. Description An awakened shrub is an ordinary shrub given sentience and mobility by the awaken spell or similar magic. Such a beast may be labelled Neutral Good or Neutral Evil depending on its goals. Meanwhile, an Awakened Parrot who accidentally casts a spell by mimicking the party wizard’s vocal components and then begins dabbling in wizardry itself may have the bond “I cast my first spell quite by accident, and now I’m excited to see what more power I have hidden within me” and the flaw “I’m terrified that my lifespan as a parrot won’t be enough to reach my potential and so I overwork myself to compensate”. An Awakened Giant Boar who betrays its keeper to join up with some mercenaries who promise it its favourite treat (them good mashed carrots) may be labelled Chaotic Neutral (or even Chaotic Evil) and given the ideal “I go wherever the eating’s good” and the flaw “I am disloyal and selfish, and will abandon anyone who does not attend to my needs”. In theory, over the last month the creature will have undertaken actions that prove its essential character. To figure that out, the DM assigns the creature a new alignment, as it simply will not do for a walking, talking member of society to go around Unaligned like a mere beast! They also assign some personality traits, an ideal, a bond, and some flaws just like they would for any NPC. It keeps all its memories and prior attachments (assuming it’s a beast), but now that it has a humanoid-level mind it must have a personality beyond mere instincts. The way I see it, the creature needs that first month to figure out who it is now that its mind has been so altered. The magic item attunement of your companions has no effect on the number of items you can attune to.Secondly, after the first 30 days that the creature spends not charmed by you (considering that they aren’t really themselves if they’re charmed by you 24/7) the DM decides on the creature’s personality that is going to be more-or-less permanent. Sanvael View User Profile View Posts Send Message (Perfect) Join Date: Posts: 1,481 Are you suggesting that the PC is an animal that has transformed into a humanoid creature, or that they will actually play as an animal If theyve transformed into a humanoid, run the normal rules. A delve into the ruins of a lost temple city where something is awakening. The term characters is not clearly defined but NPCs count as characters and this tweet from Jeremy Crawford, lead designer, implies that short rests can be taken by creatures other than PCs as "companions" can attune. during which a character does nothing more strenuous than eating, drinking, reading, and tending to wounds The only possible contention comes from the details of a short rest:Ī short rest is a period. Statistics appropriate for the awakened plant, such as the statistics for the awakened shrub or the awakened tree. Cthulhu Gargantuan aberration (great old one), chaotic evil Armor Class 25 (natural armour) Hit Points 2665 (130d20 + 1300) Speed 30 ft., fly 60 ft., swim 60 ft. the creature gains an intuitive understanding of. Since an Awakened tree uses the stat block in the monster manual it certainly qualifies as a creature.Īttuning to an item requires a creature to spend a short rest focused on only that item while being in physical contact with it. There is no restriction on which creatures can attune to magic items (but keep in mind that some items will not be usable based on the creatures body shape or ability to speak command words, etc.). Connect with us with us at on Twitter, and /1Password! We love 1Password and strive to make it the best it can be. We’re proud of these recognitions, and that millions of people love and use 1Password every day. ◆ “Best Password Manager for Families” by Tech Radar ◆ Featured on PCMAG as Best for Password Organization ◆ Named One of The World’s Greatest 100 Apps by Business Insider Your data syncs securely and automatically between your devices, and can also be accessed on the web.ġPassword has been highlighted in The New York Times, GQ, The Wall Street Journal, Forbes, The Verge, Ars Technica, Mashable, and The Guardian. Your subscription lets you use 1Password everywhere. 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Simply add your passwords, and let 1Password do the rest. The password manager that's as beautiful and simple as it is secure. Security on the go has never been this easy. 1Password 8 is rebuilt from the ground up with an all-new design and powerful personalization. Sadly, buying your way to the top is another means of getting on the NYT bestseller list. OTHER BESTSELLER LISTSīarnes & Noble (BAN), Publishers Weekly (PBW), The Boston Globe (BOG), USA Today (USA), The Denver Post (DPO), The Wall Street Journal (WSJ), The Los Angeles Times (LAT), The Washington Post (WaPo), and The American Booksellers Association ABA IndieBound (ABA). However, sales fluctuate pretty quickly, which is why it doesn’t seem that it, or any other source, can ever be 100 percent accurate. Of the above, BookScan seems to be the most reliable. The signing feature is a unique way to connect with readers: ******************** AuthorgraphĪuthorgraph allows readers to have their eBooks signed by authors while also allowing authors to get weekly emails about their books’ absolute Amazon ranking, not by category, which makes this site less in-depth on the breakdown. Storybox features software compatible with Microsoft that gives an elaborate breakdown of sales from many outlets, making them available to export for your records. Sales Rank Express is an extremely fast short-term tool that offers minute-by-minute checking for Amazon sales. Rankforest lets you compare sales performance historically, view competing titles and rank in correlation, read reviews and blogs, and track charts from several online retailers. They provide a specific breakdown as only eBooks are tracked through the eBook Tracker site. They get their information from Amazon, though they are a separate entity from Amazon (although a participant of the Amazon Services LLC Associates Program). eBook TrackerĪs the name might suggest, this site tracks eBook sales. So if publishing on Amazon, it looks at those if Barnes & Noble, it finds you on NOOK Press. OTHER SOURCES BookTrackrīookTrackr tracks your book’s specific sales. On the BookTrackr FAQ page, note that sales are pulled by looking at places your book is sold. They have also introduced Amazon Charts, which ranks the top 20 most sold and most read books of the week (again, going by actual sales rather than anticipated). The NYT numbers are based on anticipated sales for the week, while Amazon’s numbers are based on actual sales, which are determined by the hour.Īmazon’s numbers are strictly based on which books have the highest sales. To find Amazon bestsellers, see the Amazon Sales page on the Author Central feature, which pulls from BookScan. It may come as a revelation to some that Amazon uses a different system: it tracks actual sales by the hour. Northeastern also developed a model that would predict sales over time based off the first couple weeks of sales. In December, for instance, when many buy books as gifts, a substantial amount of additional units would have to be sold to land on the bestseller list. It says that during certain months the book may have to sell X number of units to make the list, given outside circumstances. This article describes a study conducted by scientists at Northeastern University. The NYT recently released an article dealing with frequently asked questions about their bestseller lists. However, we can safely assume there’s more to it, which is explored in the article below. (No big secret: indies cannot carry every or even a majority of new book titles to determine sales.) And, it focuses largely on big-name bookstores rather than small indie stores. Keep in mind that the NYT only tracks sales numbers weekly. (Top publishers know the bookstores they target and try to make sure a lot of samples go to those stores.) The NYT does not take actual sales into account, only how many books were shipped to those particular stores. The New York Times receives its info from Nielsen BookScan, which collects book sales data from select bookstores. If, like me, you wonder why, the answer is as simple as it is enigmatic: Because there is no universal system, company, or site that tracks all book sales. It’s no secret that the book industry has long been secretive about how bestsellers are actually chosen. WHEN IS A BESTSELLER REALLY A BESTSELLER? The surface chain conformations of poly(methyl methacrylate) (PMMA) at different temperatures were extensively studied by time-of-flight secondary ion mass spectrometry (ToF-SIMS). This work highlights the importance of combining SFG spectroscopy with MD simulations and ab initio calculations in understanding polymer surfaces. Our analysis shows that the weaker intensity of α-methyl groups in SFG spectra is due to a combination of smaller molecular hyperpolarizability, lower ordering, and lower surface number density. We have compared the SFG results with theoretical spectra calculated using MD simulations and ab initio calculations. The backbone methylene groups have a broad angular distribution and are disordered, independent of tacticity and temperature. For the isotactic-PMMA, the α-methyl groups are less ordered compared to their ester-methyl groups. In comparison, the MD simulation results show that both the ester-methyl and the α-methyl groups of syndiotactic-PMMA are ordered and tilted toward the surface normal. The SFG spectra for solid and melt states are very similar for both syndiotactic and isotactic PMMA. The SFG spectral features for isotactic and syndiotactic PMMA surfaces are similar, and the dominant peak in the spectra corresponds to the ester-methyl groups. Here, we combine interfacesensitive sum frequency generation spectroscopy (SFG), all-atom molecular dynamics (MD) simulations, and ab initio calculations to understand the composition and the orientation of chemical groups on poly(methyl methacrylate) (PMMA) surface as a function of tacticity and temperature. The chemical composition and molecular structure of polymeric surfaces are important in understanding wetting, adhesion, and friction. Results from conformation tensor calculations for chains with any of their segments contributing to the surface validate the visual observation. A more planar conformation of the syndiotactic PMMA along the surface (x−y plane) can be visualized through the trajectories from all-atom MD. These subtle trends in the relative angular orientation and number densities that influence the variation of surface structure with tacticity are highlighted in this article. Isotactic PMMA has the highest ratios of ester- to α-methyl. The surface number density ratios of ester-methyl to α-methyl groups show syndiotactic PMMA having the lowest value. The backbone methylene groups show a very broad angular distribution, centered along the surface plane. SFG spectroscopy also points to ester-methyl being dominant on the surface. We observe the ester-methyl groups as preferentially oriented, irrespective of tacticity, followed by the α-methyl and carbonyl groups. SFG analysis presented in part I of this joint publication measures the orientation of molecules that are in agreement with MD results. Independent quantification of the number density and orientation of chemical groups through all-atom MD presents a comprehensive model of stereoregular PMMA on the surface. Molecular structure on the surface is a complex interplay between orientation and number densities and is challenging to capture through sum frequency generation (SFG) spectroscopy alone. We quantify these effects primarily through orientation, measured as the tilt with respect to the surface normal, and the surface number densities of the α-methyl, ester-methyl, carbonyl, and backbone methylene groups. Utilizing all-atom molecular dynamics (MD), we have analyzed the effect of tacticity and temperature on the surface structure of poly(methyl methacrylate) (PMMA) at the polymer−vacuum interface. |